Studies on the photochemistry of taxol

DOI: 10.1016/S0040-4020(01)85337-0

Source and publish data:

Tetrahedron p. 8633 - 8650 (1994)

Update date:2022-08-05

Topics:

Authors:

Chen Chen

Farina Farina

Huang Huang

Gao Gao

Golik Golik

Doyle Doyle

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Article abstract of DOI:10.1016/S0040-4020(01)85337-0

Irradiation of taxol at 280 nm in a Rayonet reactor yielded a novel pentacyclic derivative containing a new bond between C-3 and C-11. The proposed mechanism involves a triplet intermediate and the first event of the oxa-di-π-methane rearrangement. Taxane

Full text of DOI:10.1016/S0040-4020(01)85337-0

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