Tetrahedron p. 8633 - 8650 (1994)
Update date:2022-08-05
Topics:
Chen
Farina
Huang
Gao
Golik
Doyle
Irradiation of taxol at 280 nm in a Rayonet reactor yielded a novel pentacyclic derivative containing a new bond between C-3 and C-11. The proposed mechanism involves a triplet intermediate and the first event of the oxa-di-π-methane rearrangement. Taxane
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(1965)
