Asymmetric Selenoxide Elimination Leading to Chiral Allenic Sulfones

DOI: 10.1021/jo00066a023

Source and publish data:

Journal of Organic Chemistry p. 3697 - 3702 (1993)

Update date:2022-08-03

Topics: Enantiomer NMR spectroscopy Chiral Catalyst Stereochemistry Asymmetric Reaction Conditions Elimination Chiral Auxiliary Sulfones Selenoxide Allenic

Authors:

Komatsu, Naoki

Murakami, Tatsushi

Nishibayashi, Yoshiaki

Sugita, Toshio

Uemura, Sakae

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Article abstract of DOI:10.1021/jo00066a023

Asymmetric oxidation of some aryl vinyl selenides (3) with Sharpless (A-C), modified Sharpless (D) or Davis oxidants (E-G) resulted in the formation of chiral allenic sulfones 5 of up to 42percent enantiomeric excess (ee) via double asymmetric induction,

Full text of DOI:10.1021/jo00066a023

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