Thermally persistent fluorosulfonyl nitrene and unexpected formation of the fluorosulfonyl radical

DOI: 10.1021/ja312073w

Source and publish data:

Journal of the American Chemical Society p. 2096 - 2099 (2013)

Update date:2022-08-06

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Authors:

Zeng, Xiaoqing

Beckers, Helmut

Willner, Helge

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Article abstract of DOI:10.1021/ja312073w

Thermally persistent triplet sulfonyl nitrene, FSO₂N, was produced in the gas phase in high yields (up to 66%) by flash vacuum pyrolysis of FSO₂N₃. Surprisingly, no rearrangement of FSO ₂N was observed, but the

Full text of DOI:10.1021/ja312073w

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