Journal of Organic Chemistry p. 3980 - 3984 (1993)
Update date:2022-08-03
Topics:
Wirz, Beat
Barner, Richard
Huebscher, Joseph
Both enantiomers of a series of synthetically valuable 2-methylglycerol derivatives have been prepared with >99percent ee using a chemoenzymatic reaction sequence.The introduction of chirality was achieved by enantioselective esterification of 1,2-O-protected 2-methylglycerol 3 or enantioselective hydrolysis of its butyryl ester 4.The enzymatic reaction proceeded with unusually high selectivity and velocity for a primary alcohol (ester) substrate.
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Doi:10.1002/chem.201503403
(2016)Doi:10.1080/10426507.2017.1295960
(2017)Doi:10.1002/ardp.19933260604
(1993)Doi:10.1055/s-1993-25880
(1993)Doi:10.1016/0022-328X(93)83113-A
(1993)Doi:10.1039/c2cc32153j
(2012)