Preparation and X-Ray Structures of Tridentate (N,N,S) Complexes of the Diazene trans- with Platinum and Palladium

DOI: 10.1039/c39930001021

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1021 - 1023 (1993)

Update date:2022-08-04

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Authors:

Chivers, Tristram

McGregor, Katherine

Parvez, Masood

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Article abstract of DOI:10.1039/c39930001021

The reaction of trans- with (C2H4)Pt(PPh3)2 or Pd(PPh3)4 in toluene produces the complexes M(PPh3)(M = Pt, Pd) in which the ligand is bonded to the metal in a tridentate (N,N,S) fashion and the diazine is formally reduced to an azine.

Full text of DOI:10.1039/c39930001021

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