Influence of the size of the phosphine ligand on primary-secondary alkyl isomerization equilibria with (Me2NCS2)Pt(PR3)(alkyl) complexes

DOI: 10.1016/0022-328X(93)83201-6

Source and publish data:

Journal of Organometallic Chemistry p. 263 - 270 (1993)

Update date:2022-08-05

Topics:

Authors:

Reger, Daniel L.

Ding, Yan

Garza, David G.

Lebioda, Lukasz

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Article abstract of DOI:10.1016/0022-328X(93)83201-6

The reactions of (Me2NCS2)Pt(Pr3)Cl with Grignard or alkyl lithium reagents lead to the preparations of (Me2NCS2)Pt(Pr3)(alkyl) (R = Me, Et, Ph, Cy, o-CH3C6H4, C6F5) complexes.The reactions are successful at or below room temperature for R = Me, Et, Ph, b

Full text of DOI:10.1016/0022-328X(93)83201-6

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