Dichlorination of (hexadehydro-diels-alder generated) benzynes and a protocol for interrogating the kinetic order of bimolecular aryne trapping reactions

DOI: 10.1021/ol403258c

Source and publish data:

Organic Letters p. 254 - 257 (2014)

Update date:2022-09-26

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Authors:

Niu, Dawen

Wang, Tao

Woods, Brian P.

Hoye, Thomas R.

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Article abstract of DOI:10.1021/ol403258c

The efficient dichlorination of benzynes prepared by the hexadehydro-Diels-Alder (HDDA) reaction is reported. Cycloisomerization of a triyne substrate in the presence of dilithium tetrachlorocuprate is shown to provide dichlorinated products A by capture

Full text of DOI:10.1021/ol403258c

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