Bulletin of the Chemical Society of Japan p. 2584 - 2587 (1990)
Update date:2022-09-26
Topics:
Miura, Katsukiyo
Oshima, Koichiro
Utimoto, Kiitiro
Proton abstraction from 3-trimethylsilylmethylthio-1-propene by butyllithium followed by treatment with iodomethane provided 1-methylthio-4-trimethylsilyl-1-butene.Meanwhile, 1-trimethylsilylmethylthio-2-butene afforded 3-methyl-4-methylthio-1-trimethylsilyl-1-butene upon successive treatment with butyllithium and iodomethane.
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