ENANTIODIFFERENTIATING TRANSFORMATION OF PROCHIRAL 1,3,5-PENTANETRIOLS CONTROLLED BY INTRAMOLECULAR VAN DER WAALS ATTRACTIONS

DOI: 10.1016/S0040-4039(00)92049-5

Source and publish data:

Tetrahedron Letters p. 1219 - 1222 (1991)

Update date:2022-09-26

Topics:

Authors:

Harada, Toshiro

Wada, Isao

Uchimura, Jun-ji

Inoue, Atsushi

Tanaka, Sachi

Oku, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)92049-5

Acetalization of prochiral 1,3,5-pentanetriol derivatives (5) with l-menthone proceeded enatioselectively (3.0-4.6:1) to give spiroacetals (6) which can be utilized as versatile chiral building blocks.

Full text of DOI:10.1016/S0040-4039(00)92049-5

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