Tetrahedron Letters p. 4935 - 4938 (1993)
Update date:2022-07-29
Topics:
Matsumoto, Kazutsugu
Shimagaki, Masayuki
Nakata, Tadashi
Oishi, Takeshi
Enzyme-mediated stereoselective aldol reaction between dihydroxyacetone phosphate (DHAP, 1) and (2R,4R)-6-benzyloxy-2,4-dimethoxyhexanal (8) was catalyzed by rabbit muscle aldolase (RAMA) to generate (3S,4R,5R,7R)-trihydroxyketone 12, which could be easily transformed to the masked polyhydroxylated compound 15 corresponding to the C-9-C-16 segment of pentamycin (6).
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Doi:10.1021/jm00024a002
(1995)Doi:10.1002/(SICI)1099-1344(199603)38:3<239::AID-JLCR831>3.0.CO;2-E
(1996)Doi:10.1021/jo01268a066
(1968)Doi:10.3987/COM-08-11626
(2009)Doi:10.1039/j39670001178
(1967)Doi:10.1039/c39930001469
(1993)
