Copper(I) Salt-Mediated Arylation of Phosphinyl-Stabilized Carbanions and Synthetic Application to Heterocyclic Compounds

DOI: 10.1021/jo00077a018

Source and publish data:

Journal of Organic Chemistry p. 7009 - 7015 (1993)

Update date:2022-08-05

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Authors:

Minami, Toru

Isonaka, Takeshi

Okada, Yoshiharu

Ichikawa, Junji

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Article abstract of DOI:10.1021/jo00077a018

The copper-mediated reaction of phosphinyl-stabilized carbanions 2a-c with aryl halides 1a-i in DMF or HMPA produced (arylmethyl)phosphonates 3-11 in good yields.Similar treatment of N-(2-iodophenyl)- and N-(2-iodophenyl)-N-methyl-α-(diethoxyphosphinyl)ac

Full text of DOI:10.1021/jo00077a018

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