
Journal of the Chemical Society. Chemical communications p. 1222 - 1223 (1993)
Update date:2022-08-04
Topics:
Darkins, Paul
McCarthy, Noreen
McKervey, M. Anthony
Ye, Tao
Homochiral N-protected α-amino glyoxals are readily accessible by oxidation of α-diazoketones derived from natural amino acids and dipeptides using dimethyldioxirane in acetone; the glyoxals can be trapped efficiently in reactions such as Wittig olefinati
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