Oxidation of α-Diazoketones derived from L-Amino Acids and Dipeptides using Dimethyldioxirane. Synthesis and Reactions of Homochiral N-Protected α-Amino Glyoxals

DOI: 10.1039/c39930001222

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1222 - 1223 (1993)

Update date:2022-08-04

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Authors:

Darkins, Paul

McCarthy, Noreen

McKervey, M. Anthony

Ye, Tao Ye, Tao

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Article abstract of DOI:10.1039/c39930001222

Homochiral N-protected α-amino glyoxals are readily accessible by oxidation of α-diazoketones derived from natural amino acids and dipeptides using dimethyldioxirane in acetone; the glyoxals can be trapped efficiently in reactions such as Wittig olefinati

Full text of DOI:10.1039/c39930001222

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