Synthesis of Optically Active Lactones and 3-Cyclopentenone from Optically Active 3,3-Dialkyl-4-thianones

DOI: 10.1246/bcsj.66.1743

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1743 - 1753 (1993)

Update date:2022-09-26

Topics:

Authors:

Matsuyama, Haruo

Fujii, Sana

Nakamura, Yoshihiro

Kikuchi, Koichi

Ikemoto, Isao

Kamigata, Nobumasa

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Article abstract of DOI:10.1246/bcsj.66.1743

The Optically active 3,3-dialkyl-4-thianones 3 and 4 were prepared in moderate yields with about 90percent enantiomeric purity using an asymmetric process involving a Michael-type alkylation of chiral 3-alkyl-4-thianimines with methyl vinyl ketone or meth

Full text of DOI:10.1246/bcsj.66.1743

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