Catalytic Asymmetric Construction of Morpholines and Piperazines by Palladium-Catalyzed Tandem Allylic Substitution Reactions

DOI: 10.1021/jo00076a052

Source and publish data:

Journal of Organic Chemistry p. 6826 - 6832 (1993)

Update date:2022-08-05

Topics: Reactions Asymmetric Palladium-Catalyzed Tandem Catalytic Construction Morpholines Piperazines Allylic Substitution

Authors:

Uozumi, Yasuhiro

Tanahashi, Asako

Hayashi, Tamio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00076a052

Reaction of 1,4-diacetoxy-cis-2-butene (1a) with 2-(benzylamino)ethanol (2a) was catalyzed by a palladium complex (5 mol percent) coordinated with (R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl to give optically active (R)-4-benzyl-2-vinylmorpholine (3a)

Full text of DOI:10.1021/jo00076a052

Products guided by the article

Product name:N-[2-((R)-1-Hydroxymethyl-propylamino)-ethyl]-4-methyl-benzenesulfonamide

Cas No:152877-82-2

R&D Labs maybe for 152877-82-2

Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Sinonine Industry Co.,Ltd

Contact:86+21-56421993

Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
ClickChem Technology Co., Limited

Contact:+86-0310-6519966/0531-52893837

Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada

Relevant to this article

Syntheses of [6,7-¹⁵N]-adenosine, [6,7-¹⁵N]-2'-deoxyadenosine, and [7-¹⁵N]-hypoxanthine

Doi:10.1021/ja00152a006
(1995)
Kinetics and Mechanism of the Nucleophilic Displacement Reactions of Chloroacetanilide Herbicides: Investigation of α-Substituent Effects

Doi:10.1021/jf030290d
(2004)
Crotonic, cynnamic, and propiolic acids motifs in the synthesis of thiopyrano[2,3-d][1,3]thiazoles via hetero-Diels-Alder reaction and related tandem processes

Doi:10.1016/j.tet.2013.11.083
(2014)
Synthesis of analogues of 3'-deoxypsicothymidine

Doi:10.1080/15257779508012374
(1995)
Design and Synthesis of Fused Pyridine Building Blocks for Automated Library Generation

Doi:10.1002/cmdc.202000852
(2021)
Discovery of novel diarylpyrimidines as potent HIV NNRTIs via a structure-guided core-refining approach

Doi:10.1016/j.ejmech.2014.04.036
(2014)

Article Doi