Catalytic Asymmetric Construction of Morpholines and Piperazines by Palladium-Catalyzed Tandem Allylic Substitution Reactions

DOI: 10.1021/jo00076a052

Source and publish data:

Journal of Organic Chemistry p. 6826 - 6832 (1993)

Update date:2022-08-05

Topics: Reactions Asymmetric Palladium-Catalyzed Tandem Catalytic Construction Morpholines Piperazines Allylic Substitution

Authors:

Uozumi, Yasuhiro

Tanahashi, Asako

Hayashi, Tamio

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Article abstract of DOI:10.1021/jo00076a052

Reaction of 1,4-diacetoxy-cis-2-butene (1a) with 2-(benzylamino)ethanol (2a) was catalyzed by a palladium complex (5 mol percent) coordinated with (R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl to give optically active (R)-4-benzyl-2-vinylmorpholine (3a)

Full text of DOI:10.1021/jo00076a052

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