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Direct Evidence for Electrochemically Induced, Reversible, Proton Transfer involving a Quinone/Hydroquinone Redox Couple

DOI: 10.1039/c39930001652

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1652 - 1654 (1993)

Update date:2022-09-26

Topics:

Authors:

Wang, R.Wang, R.

Keyes, T. E.Keyes, T. E.

Hage, R.Hage, R.

Schmehl, R. H.Schmehl, R. H.

Vos, J. G.Vos, J. G.

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Article abstract of DOI:10.1039/c39930001652

The complex (PF6) , exhibits electrochemically induced proton transfer between the hydroquinone moiety and the triazole; evidence for this phenomenon is derived from electrochemical and spectroelectrochemical experiments, and suggests that the transfer occurs intramolecularly via a hydrogen-bridge formation between the hydroquinone and triazole.

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