Synthesis of optically active amino azapenams by the photolytic reaction of chromium aminocarbene complexes with N-protected imidazolines

DOI: 10.1016/S0040-4020(01)87268-9

Source and publish data:

Tetrahedron p. 5549 - 5563 (1993)

Update date:2022-08-04

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Authors:

Ronan, Baptiste

Hegedus, Louis S.

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Article abstract of DOI:10.1016/S0040-4020(01)87268-9

Photolysis of optically active aminocarbene chromium complexes with N-protected imidazolines produced α-amino-N-protected azapenams in good yield and with high diastereoselectivity. Removal of the protecting group resulted in cleaving of the β-lactam to g

Full text of DOI:10.1016/S0040-4020(01)87268-9

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