Diels-Alder reactions enhanced diastereofacial selectivity in 5.0 M LiCIO4-Et2O approach to the construction of the isoindolone nucleus of cytochalasans

DOI: 10.1016/S0040-4039(00)60127-2

Source and publish data:

Tetrahedron Letters p. 7367 - 7370 (1993)

Update date:2022-08-05

Topics:

Authors:

Grieco Grieco

Beck Beck

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Article abstract of DOI:10.1016/S0040-4039(00)60127-2

Dienes of type 2 undergo highly diastereoselective Diels-Alder reactions with maleic anhydride in 5.0 M lithium perchlorate-diethyl ether giving rise to isobenzofurandiones which upon exposure to trifluoroacetic acid generate tetrahydroisoindolones.

Full text of DOI:10.1016/S0040-4039(00)60127-2

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