Transition Metal Phosphine Complexes Possessing Phase Transfer Function. Preparation and Reactivities of Palladium Complexes Containing Quaternary Ammonium Groups

DOI: 10.1246/cl.1994.1057

Source and publish data:

Chemistry Letters p. 1057 - 1060 (1994)

Update date:2022-08-04

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Authors:

Okano, Tamon

Harada, Nobuyuki

Kiji, Jitsuo

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Article abstract of DOI:10.1246/cl.1994.1057

A new type of phosphine ligands (L) bearing quaternary ammonium as a functional group was synthesized.Their palladium complexes, PdBr2L2, readily underwent halogen exchange with powdered NaI under two-phase conditions, and efficiently catalyzed the fluorocarbonylation of phenyl bromide with powdered KF at atmospheric pressure of CO.

Full text of DOI:10.1246/cl.1994.1057

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