Stereoselective alkynylation of chiral benzaldehyde chromium tricarbonyl complexes. Synthesis of optically active alkynyl alcohols

DOI: 10.1016/S0040-4039(00)61518-6

Source and publish data:

Tetrahedron Letters p. 7943 - 7946 (1993)

Update date:2022-08-04

Topics:

Authors:

Baldoli, Clara

Del Buttero, Paola

Licandro, Emanuela

Maiorana, Stefano

Papagni, Antonio

Torchio, Maurizio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)61518-6

Addition of lithium acetylides and ethynyl magnesium bromide to chiral ortho substituted benzaldehyde tricarbonylchromium complexes 1-3 gives alkynyl alcohols 4-7 in good yields and with complete stereoselection.

Full text of DOI:10.1016/S0040-4039(00)61518-6

Products guided by the article

Product name:Benzenemethanol, 2-methoxy-a-[(trimethylsilyl)ethynyl]-

Cas No:153889-90-8

R&D Labs maybe for 153889-90-8

HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD

Contact:+86-571-88932183

Address:Hangzhou
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Goldwills Pharmaceuticals Co., Ltd.

Contact:0916-2237889 13991621155

Address:North Suburb of Hanzhong city, Shaanxi Province
Mollt Biochem Co., Ltd(expird)

Contact:+86-21-38682181

Address:shanghai ,china
Wuxi Forest Biological Co.,Ltd

Contact:+86-510-81602300

Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.

Relevant to this article

Development of a concise, asymmetric synthesis of a smoothened receptor (smo) inhibitor: Enzymatic transamination of a 4-piperidinone with dynamic kinetic resolution

Doi:10.1021/ol403630g
(2014)
Highly Diastereoselective Synthesis of (-)-Petasinecine via Ireland-Claisen-Type Rearrangement

Doi:10.1016/0040-4039(93)88100-W
(1993)
An Enantiospecific Entry to Indolizidines by Intramolecular Acylation of N-Pyrrole Esters

Doi:10.1016/S0040-4039(00)76698-6
(1994)
Tungstate sulfuric acid (TSA)/ KMnO₄ as a novel heterogeneous system for rapid deoximation

Doi:10.3390/11090720
(2006)
Doi:10.1021/jo01348a538
(1966)
Synthesis of (R)- and (S)-5-(hydroxymethyl)-3-isopropyloxazolidin-2-one, intermediates in the preparation of optically active β-blockers

Doi:10.1002/hlca.19940770127
(1994)

Article Doi