A cobalt-phosphine complex as mediator in the formation of carbon-carbon bonds

DOI: 10.1021/jo00080a001

Source and publish data:

Journal of Organic Chemistry p. 1 - 3 (1994)

Update date:2022-07-31

Topics:

Authors:

Orsini Orsini

Pelizzoni

Pulici Pulici

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Article abstract of DOI:10.1021/jo00080a001

The tetrakis(trimethylphospine)cobalt(0) complex, [Co{P(CH₃)₃}₄], in either stoichiometric or catalytic amounts, was shown to be an efficient mediator for a one-pot Reformatsky-type reaction between activated halogen derivatives (esters, amides, lactones) and carbonyl compounds (aldehydes, ketones) to produce a variety of alcohols.

Full text of DOI:10.1021/jo00080a001

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