A cobalt-phosphine complex as mediator in the formation of carbon-carbon bonds

DOI: 10.1021/jo00080a001

Source and publish data:

Journal of Organic Chemistry p. 1 - 3 (1994)

Update date:2022-07-31

Topics:

Authors:

Orsini Orsini

Pelizzoni

Pulici Pulici

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00080a001

The tetrakis(trimethylphospine)cobalt(0) complex, [Co{P(CH₃)₃}₄], in either stoichiometric or catalytic amounts, was shown to be an efficient mediator for a one-pot Reformatsky-type reaction between activated halogen derivatives (esters, amides, lactones) and carbonyl compounds (aldehydes, ketones) to produce a variety of alcohols.

Full text of DOI:10.1021/jo00080a001

Products guided by the article

Product name:3-(α-naphthyl)-3-hydroxy-tert-butylpropanoate

Cas No:153579-34-1

R&D Labs maybe for 153579-34-1

Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China
SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China
Shanghai Hongbang Medical Technology CO.,. Ltd

Contact:13671516988 /18917636693

Address:Room1, No67 Building, Yongde Road369, Wujing Town, Minhang Districy, Shanghai CIty, China.

Relevant to this article

Cyclic analogs of chemotactic formylpeptides. I.: Synthesis and biological activity of For-Cys-Leu-Phe-Cys-OMe

Doi:10.1002/ardp.19933261208
(1993)
Plug-and-play fluorophores extend the spectral properties of spinach

Doi:10.1021/ja410819x
(2014)
Formation of a Pseudo-β-hairpin motif utilizing the Ant-pro reverse turn: Consequences of stereochemical reordering

Doi:10.1039/c3ob42016g
(2014)
Syntheses of S-enantiomers of hanishin, longamide B, and longamide B methyl ester from L-aspartic acid β-methyl ester: Establishment of absolute stereochemistry

Doi:10.1021/jo051555l
(2005)
Synthesis of diastereoisomeric pairs of novel analogues of d4T having an isochroman glycon moiety; their enzymatic kinetic resolution, their enantiopure synthesis, molecular modeling and NMR structural study

Doi:10.1016/j.tet.2005.07.084
(2005)
New, general, and practical preparation of methyl ketones via the direct coupling of amides with CH₂CI₂ promoted by TiCI ₄/Mg

Doi:10.1021/ol8004326
(2008)

Article Doi