Diazaborolidines, a new class of enantioselective organoboron catalytic agents

DOI: 10.1016/S0957-4166(00)80097-X

Source and publish data:

Tetrahedron Asymmetry p. 2335 - 2338 (1993)

Update date:2022-07-30

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Authors:

Froelich

Bonin Bonin

Quirion Quirion

Husson Husson

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Article abstract of DOI:10.1016/S0957-4166(00)80097-X

Diazaborolidines 6 and 9, derived from 2-aminomethyl-piperidine, have been prepared in an optically pure form from 2-cyano-6-phenyl oxazolopiperidine 3. The best results for the asymmetric reduction of acetophenone (yield > 95%, 72% ee) have been obtained

Full text of DOI:10.1016/S0957-4166(00)80097-X

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Product name:N-[(S)-1-((R)-2-Hydroxy-1-phenyl-ethyl)-piperidin-2-ylmethyl]-2,4,6-triisopropyl-benzenesulfonamide

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