Journal of Organometallic Chemistry p. 103 - 112 (1994)
Update date:2022-08-04
Topics:
Hahn, F. Ekkehardt
Tamm, Matthias
The tripodal aromatic triisocyanides HC(CH2CH2CH2O-2-C6H4NC)3 (5) and H3C-C(CH2O-2-C6H4NC)3 (6) react with (C7H8)W(CO)3 to give the chelate complexes fac-<(5)W(CO)3> (15) und fac-<(6)W(CO)3> (16). 15 was shown by NMR spectroscopy to be a 5:3 mixture of two isomers, in which the central methine group of the ligand adopts either the in- (15a) or the out-configuration (15b) respectively.The molecular structure of 16 in which 6 adopts the out-configuration exclusively, has been determined by X-ray structure analysis. Key words: Isocyanide; Tungsten; X-ray diffraction
View MoreWuhan Benjamin Pharmaceutical Chemical Co.,Ltd
Contact:86-27-52341789
Address:Room 1518 B suite, optical valley time square, No 111 Guanshan Road, Hongshan District,Wuhan,Hubei Province,China.
Contact:+44 7958 511245
Address:PO Box 469, Manchester, UK
Longhui qunfeng Chemical Co., Ltd
Contact:86-731-82173407
Address:South-east Industrial Park, Longhui County, Hunan Province, China
Contact:027-87677569
Address:Room 2203, yujingmingmen Buidling One, xiongchu Road, wuhan city, hubei province, China
TIANJIN GST CHEMICAL TECHNOLOGY CO., LTD
Contact:+86-22-25210964
Address:Room. 208, No. -12-C, No. 13, Xinbei Road, Tanggu District, New Haixin Area, Tianjin City, China
Doi:10.1016/0022-328X(94)80045-6
(1994)Doi:10.1021/jo402742k
(2014)Doi:10.1021/ja970743t
(1997)Doi:10.1021/jm00037a016
(1994)Doi:10.1007/s11172-013-0170-6
(2013)Doi:10.1039/c3ra46428h
(2014)
