Tetrahedron Letters p. 7865 - 7868 (1993)
Update date:2022-08-16
Topics: Stereoselective Radical Disproportionation Tertiary Alkene Alkane Organic synthesis Reaction Conditions Steric Effects Electronic effects
Porter, Ned A.
Rosenstein, Ian J.
Radicals α to the carbonyl of ethyl 3,4,4-trimethylpentanoate couple with little stereoselectivity while analogous tertiary radicals derived from ethyl 2,3,4,4-tetramethylpentanoate disproportionate at 25°C to give the corresponding alkene and alkane. The
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