Cyclization of γ,δ-Epoxy-α-cyanosulphones. A Simple, Diastereoselective Route to Cyclopropane Carboxylic Acids.

DOI: 10.1016/0040-4039(93)85066-6

Source and publish data:

Tetrahedron Letters p. 6443 - 6446 (1993)

Update date:2022-08-03

Topics:

Authors:

Benedetti, Fabio

Berti, Federico

Risaliti, Amerigo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(93)85066-6

cyclisation of α-cyano-α-sulphonyl-γ,δ-epoxy carbanions proceeds with high yields and complete diastereoselectivity, to yield cyclopropanolactones, useful intermediates in the synthesis of cis-substituted cyclopropane carboxylic acids.

Full text of DOI:10.1016/0040-4039(93)85066-6

Products guided by the article

Product name:<2-(phenylsulfonyl)-2-cyanoethyl>oxirane

Cas No:154910-03-9

R&D Labs maybe for 154910-03-9

Chengdu Yunyi International Trade Co., Ltd

Contact:

Address:china
lianyungang jinkang pharmaceutical technology co., ltd.

Contact:008651885445517

Address:Jinshan industrial park, Ganyu county, Lianyungang, Jiangsu Province, 222115, China
Sino Rarechem Labs Co.Ltd

Contact:+86-0512-62857507

Address:Boji Science Park, No1688C,Taishan road, Suzhou ,China
Shijiazhuang Sdyano Fine Chemical Co., Ltd

Contact:+86-311-89830448

Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
Eastar Chemical Corporation

website:http://www.eastarchem.com/

Contact:1-800-898-2436

Address:1215 K Street, STE 1700

Relevant to this article

Synthesis and Characterization of Models for the 2,4,5-Trihydroxyphenylalanine (TOPA)-Derived Cofactor of Mammalian Copper Amine Oxidases, and Initial Amine Reactivity Studies

Doi:10.1021/jo00088a023
(1994)
Asymmetric synthesis. XXX. Synthesis of 3-substituted piperidines from chiral non-racemic lactams

Doi:10.1016/S0040-4039(00)77162-0
(1994)
Preparation of new 2,4-disubstituted oxazoles

Doi:10.1016/S0040-4039(00)73043-7
(1994)
1-Azatriene cyclisation as a route to annelated pyrido[4,3-b]indoles

Doi:10.1016/S0040-4020(97)00117-8
(1997)
Control of electron demand in the cycloadditions of 2(H)-1,4-oxazin-2-ones

Doi:10.1016/j.tetlet.2004.07.105
(2004)
Enantioselective synthesis of N-Boc and N-Fmoc protected diethyl 4-phosphono(difluoromethyl)-L-phenylalanine; agents suitable for the solid-phase synthesis of peptides containing nonhydrolyzable analogues of O-phosphotyrosine

Doi:10.1016/S0040-4039(00)75835-7
(1994)

Article Doi