Recueil des Travaux Chimiques des Pays-Bas p. 535 - 548 (1993)
Update date:2022-08-02
Topics:
Scherer, T.
Hielkema, W.
Krijnen, B.
Hermant, R. M.
Eijckelhoff, C.
et al.
We report a two-step synthesis for N-aryl- and N-alkyl-substituted 4-piperidones, in which the N substituent can easily be varied.A number of intramolecular donor-acceptor systems was synthesized from these piperidones by conversion of the carbonyl functionality.The influence of the N-aryl donor on the electronic absorption and fluorescence spectra was investigated systematically.It was concluded that some systems can be used as efficient fluorescent probes with a high sensitivity for solvent polarity.
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Doi:10.1021/acs.orglett.1c02215
(2021)Doi:10.1021/ja00990a051
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