BN cleavage of the azoniaboratacyclopropane ring by H2O and by carbonyl and nitrile derivatives: crystal structure of (CF3)2B(OH)CH(SiMe3)NHMe2, and (MeC(O)NH)(CF3)2BCH(SiMe3)NHMe2

DOI: 10.1016/0022-328X(94)88001-8

Source and publish data:

Journal of Organometallic Chemistry p. 1 - 12 (1994)

Update date:2022-07-29

Topics:

Authors:

Ansorge, A.

Brauer, D.J.

Buerger, H.

Hagen, T.

Pawelke, G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)88001-8

1,1-Dimethyl-2,2-bis(trifluoromethyl)azoniaboratacyclopropane derivatives (R=H (I), SiMe3 (II)) react with H2O with cleavage of the NB bond to form (CF3)2B(OH)CHRNHMe2 (R=H (III), SiMe3 (IV)).Carbonyl compounds R¹R²C=O are

Full text of DOI:10.1016/0022-328X(94)88001-8

Products guided by the article

Product name:2,2-bis(trifluoromethyl)-4,4-dimethyl-5-phenyl-3-trimethylsilyl-1-aza-4-azonia-2-boratacyclopentene

Cas No:154972-65-3

R&D Labs maybe for 154972-65-3

Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China
ShangHai Soyoung Biotechnology Inc

website:http://www.soyoungbio.com

Contact:+86-21-69893009

Address:shanghai
Anhui Sholon New Material Technology Co., Ltd.

website:http://www.sholonchem.com

Contact:+86-550-5261666

Address:4/F Block B, Beijing Chemical Building.No.520 Tianrun Road ,Science & Education Town Wujin District, Changzhou City Jiangsu Province
SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
Chengdu Aslee Biopharmaceuticals, Inc

Contact:18608018419

Address:Chengdu Aslee Biopharmaceuticals, Inc

Relevant to this article

Chemosensing of chloride based on a luminescent platinum(II) NCN pincer complex in aqueous media

Doi:10.1021/om4007054
(2014)
2-Cycloalkyl phenoxyacetic acid CRTh2 receptor antagonists

Doi:10.1016/j.bmcl.2007.05.019
(2007)
Two-Step Stereoselective Conversion of 5-Monosubstituted 1,3-Dioxolan-4-ones into Selectively Protected 2,3-Erythro-1,2,3-Triols. A Route to Polyhydroxylated Molecules

Doi:10.1016/S0040-4039(00)77164-4
(1994)
A flexible, highly efficient method for the preparation of homochiral oxazaphospholidine-boranes

Doi:10.1016/S0040-4020(01)80637-2
(1994)
Substrates as Electron-Donor Precursors: Synthesis of Naphtho-Fused Oxindoles via Benzannulation of 2-Halobenzaldehydes and Indolin-2-ones

Doi:10.1021/acs.orglett.6b02515
(2016)
Total synthesis of 7′-desmethylkealiiquinone, 4′- desmethoxykealiiquinone, and 2-deoxykealiiquinone

Doi:10.1021/jo4027337
(2014)

Article Doi