BN cleavage of the azoniaboratacyclopropane ring by H2O and by carbonyl and nitrile derivatives: crystal structure of (CF3)2B(OH)CH(SiMe3)NHMe2, and (MeC(O)NH)(CF3)2BCH(SiMe3)NHMe2

DOI: 10.1016/0022-328X(94)88001-8

Source and publish data:

Journal of Organometallic Chemistry p. 1 - 12 (1994)

Update date:2022-07-29

Topics:

Authors:

Ansorge, A.

Brauer, D.J.

Buerger, H.

Hagen, T.

Pawelke, G.

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Article abstract of DOI:10.1016/0022-328X(94)88001-8

1,1-Dimethyl-2,2-bis(trifluoromethyl)azoniaboratacyclopropane derivatives (R=H (I), SiMe3 (II)) react with H2O with cleavage of the NB bond to form (CF3)2B(OH)CHRNHMe2 (R=H (III), SiMe3 (IV)).Carbonyl compounds R¹R²C=O are

Full text of DOI:10.1016/0022-328X(94)88001-8

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