Two-Step Stereoselective Conversion of 5-Monosubstituted 1,3-Dioxolan-4-ones into Selectively Protected 2,3-Erythro-1,2,3-Triols. A Route to Polyhydroxylated Molecules

DOI: 10.1016/S0040-4039(00)77164-4

Source and publish data:

Tetrahedron Letters p. 2537 - 2540 (1994)

Update date:2022-07-29

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Authors:

Untersteller, Edouard

Xin, Yan Chao

Sinay, Pierre

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Article abstract of DOI:10.1016/S0040-4039(00)77164-4

5-Monosubstituted 1,3-dioxolan-4-one 1 are stereoselectively converted into selectively protected 2,3-erythro-1,2,3-triols 3 via Tebbe methylenation, followed by hydroboration-oxidation.Key words: 1,3-dioxolan-4-one derivatives, Tebbe methylenation, polyo

Full text of DOI:10.1016/S0040-4039(00)77164-4

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