Two-Step Stereoselective Conversion of 5-Monosubstituted 1,3-Dioxolan-4-ones into Selectively Protected 2,3-Erythro-1,2,3-Triols. A Route to Polyhydroxylated Molecules

DOI: 10.1016/S0040-4039(00)77164-4

Source and publish data:

Tetrahedron Letters p. 2537 - 2540 (1994)

Update date:2022-07-29

Topics:

Authors:

Untersteller, Edouard

Xin, Yan Chao

Sinay, Pierre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)77164-4

5-Monosubstituted 1,3-dioxolan-4-one 1 are stereoselectively converted into selectively protected 2,3-erythro-1,2,3-triols 3 via Tebbe methylenation, followed by hydroboration-oxidation.Key words: 1,3-dioxolan-4-one derivatives, Tebbe methylenation, polyo

Full text of DOI:10.1016/S0040-4039(00)77164-4

Products guided by the article

Product name:(5S)-2,2-dimethyl-4-methylene-5-phenyl-1,3-dioxolane

Cas No:156517-44-1

R&D Labs maybe for 156517-44-1

Forsman Scientific(Beijing)co.,Ltd.

Contact:+86-10-64646565

Address:Rm No.1301, Building-2, No. A-13 Beiyuan Road, Chaoyang District Beijing, China, PR,
Jiangsu Willing Bio-Tech Co ltd

website:http://www.willingbio.com/

Contact:+86 18796908173

Address:No 18 Guoqiao Road
Chinapeptides Co,. Ltd

Contact:+86-021-50792271

Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Zhengzhou Xinlian Chemical Tech Co. ,Ltd

Contact:0371-65771781 021-52042910

Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai
Taizhou Huading Chemical Co.,Ltd(expird)

Contact:+86-576-88583898

Address:Economic&Technology development zone,Taizhou City,Zhejiang Province,China

Relevant to this article

Copper-catalyzed synthesis of 2H-thiopyran derivatives from alkynes, sulfonyl azides, carbon disulfide, and malononitrile

Doi:10.1002/hlca.201200600
(2013)
Doi:10.1021/ja01162a039
(1950)
Generation of complexity in fungal terpene biosynthesis: Discovery of a multifunctional cytochrome P450 in the fumagillin pathway

Doi:10.1021/ja500881e
(2014)
The new NH-acid HN(C₆F₅)(C(CF₃) ₃) and its crystalline and volatile alkaline and earth alkaline metal salts

Doi:10.1021/ic5001717
(2014)
Evaluation of glucose-linked nitroxide radicals for use as an in vivo spin-label probe

Doi:10.1016/j.saa.2014.01.047
(2014)
Alkyl-for-iodide metathesis initiated by dissociation of the phosphine ligand from CpCr(NO)(PPh₃)I

Doi:10.1021/ja00096a029
(1994)

Article Doi