Asymmetric anti-selective aldol reactions of titanium Z-enolates derived from N-alkylideneglycinamides bearing a 2,2-dimethyloxazolidine chiral controller

DOI: 10.1016/S0040-4039(00)61414-4

Source and publish data:

Tetrahedron Letters p. 8293 - 8296 (1993)

Update date:2022-07-30

Topics:

Authors:

Kanemasa, Shuji

Mori, Takashi

Tatsukawa, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)61414-4

Asymmetric aldol reactions of titanium Z-enolates of N-diphenylmethylene derivatives of glycinamides derived from (4S)-2,2-dimethyloxazolidine chiral auxiliaries are highly ul,ul-1,4-inductive. Hydrolytic removal of the chiral auxiliary from the aldol add

Full text of DOI:10.1016/S0040-4039(00)61414-4

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