Oxidation of primary alcohols to acyl fluorides using BrF3

DOI: 10.1016/0022-1139(95)03365-3

Source and publish data:

Journal of Fluorine Chemistry p. 145 - 147 (1996)

Update date:2022-08-03

Topics:

Authors:

Rozen, Shlomo

Ben-David, Iris

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Article abstract of DOI:10.1016/0022-1139(95)03365-3

Aliphatic and alicyclic primary alcohols when treated with BrF₃ were rapidly oxidized to the corresponding acyl fluorides. The reaction is of an ionic nature. The main by-product was found to be the symmetrical ester which originates from the reaction between the acyl fluoride and unreacted starting alcohol.

Full text of DOI:10.1016/0022-1139(95)03365-3

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