Novel Intramolecular Michael Addition of Organomercury Halides Mediated by a Lewis Acid and Halide Anion

DOI: 10.1039/c39940000081

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Journal of the Chemical Society. Chemical communications p. 81 - 82 (1994)

Update date:2022-08-03

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Authors:

Takemoto, Yoshiji

Ohra, Taiichi

Yonetoku, Yasuhiro

Nishimine, Kazumi

Iwata, Chuzo

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Article abstract of DOI:10.1039/c39940000081

Alkylmercury chloride bearing electron-deficient olefin 3 undergoes a Michael reaction intramolecularly via hypervalent intermediates 10 by the double activation method mediated by a Lewis acid and iodide anion to provide spirocyclic compounds 4 and 5.

Full text of DOI:10.1039/c39940000081

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