Pd2+-promoted cyclization in tetracyclic diterpene synthesis highly diastereoselective formal total synthesis of (±)-stemodin

DOI: 10.1016/S0040-4039(00)73821-4

Source and publish data:

Tetrahedron Letters p. 5947 - 5950 (1993)

Update date:2022-09-26

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Authors:

Toyota, Masahiro

Seishi, Takashi

Fukumoto, Keiichiro

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Article abstract of DOI:10.1016/S0040-4039(00)73821-4

Intramolecular Diels-Alder reaction of the triene 5 and Pd²⁺-promoted cyclization reaction of the olefinic silyl enol ether of 10 have been utilized as the key steps for a conceptually new, highly diastereocontrolled formal total synthesis of (

Full text of DOI:10.1016/S0040-4039(00)73821-4

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