Pd2+-promoted cyclization in tetracyclic diterpene synthesis highly diastereoselective formal total synthesis of (±)-stemodin

DOI: 10.1016/S0040-4039(00)73821-4

Source and publish data:

Tetrahedron Letters p. 5947 - 5950 (1993)

Update date:2022-09-26

Topics:

Authors:

Toyota, Masahiro

Seishi, Takashi

Fukumoto, Keiichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73821-4

Intramolecular Diels-Alder reaction of the triene 5 and Pd²⁺-promoted cyclization reaction of the olefinic silyl enol ether of 10 have been utilized as the key steps for a conceptually new, highly diastereocontrolled formal total synthesis of (

Full text of DOI:10.1016/S0040-4039(00)73821-4

Products guided by the article

Product name:2-[1-Hydroxy-meth-(E)-ylidene]-4-((E)-penta-2,4-dienyl)-cyclohexanone

Cas No:155501-63-6

R&D Labs maybe for 155501-63-6

Winchem Industrial Co. Ltd.(expird)

Contact:86-574-83851061 86-574-87083208

Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Jinan Boss Chemical Industry Co., Ltd.【revoke the business license】

website:http://www.chemboss.com.cn

Contact:+86-531-58591595

Address:No2.Hualong Road, Jinan, China
Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Jiangsu Fengshan Group Co., Ltd.

Contact:86-25-86558671

Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China

Relevant to this article

Palladium-catalyzed P(O)R₂ directed C-H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

Doi:10.1039/c3cc49050e
(2014)
Enantioselective synthesis of both diastereomers including the α-alkoxy-β-hydroxy-β-methyl(phenyl) units, by chiral tin(II) Lewis acid-mediated asymmetric aldol reactions

Doi:10.1016/S0040-4020(01)85531-9
(1994)
First Synthesis of Sulfonyl Substituted Tricarbonyl(η⁶-arene)chromium(0) Complexes

Doi:10.1039/c39940000753
(1994)
Polar cycloaddition of 2-pyridinetellurium trichloride to multiple bonds

Doi:10.1007/s11172-013-0139-5
(2013)
The development of carbon-carbon bond forming reactions of aminal radicals

Doi:10.1016/j.tet.2014.12.067
(2015)
Novel Carboline Derivatives as Potent Antifungal Lead Compounds: Design, Synthesis, and Biological Evaluation

Doi:10.1021/ml400492t
(2014)

Article Doi