A NOVEL APPROACH TO THE ASYMMETRIC SYNTHESIS OF MANZAMINE A. CONSTRUCTION OF THE TETRACYCLIC ABCE RING SYSTEM

DOI: 10.1016/S0040-4039(00)75792-3

Source and publish data:

Tetrahedron Letters p. 691 - 694 (1994)

Update date:2022-08-04

Topics:

Authors:

Martin, Stephen F.

Liao, Yusheng

Wong, Yueling

Rein, Tobias

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Article abstract of DOI:10.1016/S0040-4039(00)75792-3

The enantiomerically pure tetracyclic ABCE subunit of manzamine A has been constructed by an intramolecular Diels-Alder reaction of the vinylogous imide 13 to give the ABC tricyclic core 14; elaboration of 14 into 16 followed by a novel olefin metathesis reaction to form the azocine ring then delivered the tetracycle 17.

Full text of DOI:10.1016/S0040-4039(00)75792-3

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