
Tetrahedron Letters p. 691 - 694 (1994)
Update date:2022-08-04
Topics:
Martin, Stephen F.
Liao, Yusheng
Wong, Yueling
Rein, Tobias
The enantiomerically pure tetracyclic ABCE subunit of manzamine A has been constructed by an intramolecular Diels-Alder reaction of the vinylogous imide 13 to give the ABC tricyclic core 14; elaboration of 14 into 16 followed by a novel olefin metathesis reaction to form the azocine ring then delivered the tetracycle 17.
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