Tetrahedron Letters p. 1879 - 1882 (1994)
Update date:2022-07-29
Topics:
Wu, Ming-Jung
Lin, Chi-Fong
Wu, Jiun-Sheng
Chen, Huey-Ting
Molecules that contains (Z)-7-sulfonyl-3-hexen-1,5-diyne functionalities undergoes base-catalyzed isomerization to (Z)-eneyne-allene-sulfone and subsequent Myers cyclization to form aromatic products, presumably via a biradical intermediate. In the presence of a nucleophile, (Z)-eneyne-allene- sulfone served as a good Michael acceptor.
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Doi:10.3184/174751913X13844245553486
(2013)Doi:10.1039/c3cc49558b
(2014)Doi:10.1002/ejoc.202100001
(2021)Doi:10.1016/S0040-4039(00)76788-8
(1994)Doi:10.1016/j.tet.2014.01.011
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