Tetrahedron Asymmetry p. 41 - 44 (1994)
Update date:2022-08-05
Topics:
Stephan
Rocher
Aubouet
Pourcelot
Cresson
Chiral β-aryl carboxylic acids, prepared by Michael addition of organocuprates to chiral unsaturated imides, are transformed into chiral 3- alkyl-4-benzoyloxyindan-1-ones via two intramolecular acylations, with intermediate formation of chiral 3-alkylindanones and corresponding dihydrocoumarins. The 3-(S)-ethyl-4-benzoyloxyindanone is transformed into(+)-3-(S)-(2,6-dimethoxyphenyl)pentanoic acid.
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Doi:10.1002/jlcr.1565
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(2016)Doi:10.1021/acscatal.8b02081
(2018)Doi:10.1021/jm00037a011
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