Organic Letters p. 1200 - 1203 (2014)
Update date:2022-08-05
Topics:
Yu, Songjie
Li, Xingwei
A rhodium(III)-catalyzed C-C coupling between 2-vinyloxiranes and arenes directed by different chelating groups has been realized via a C-H activation pathway. This reaction proceeded under conditions with a low catalyst loading, and allylic alcohols were isolated as the coupling products. A series of benzoazepanes has been synthesized by following this coupling.
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