Journal of the Chemical Society. Perkin transactions I p. 289 - 294 (1994)
Update date:2022-07-29
Topics:
Sakakura, Toshiyasu
Hara, Masayasu
Tanaka, Masato
Diazonium salts efficiently serve as electrophilic aminating reagents of esters.The reaction of arenediazonium tetrafluoroborates with ketene silyl ketals yielded α-azo or α-hydrazono esters in good to excellent yields under very mild conditions.Hydrogenation of those esters gave α-amino esters quantitatively.
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