The asymmetric synthesis of allylic alcohols using a recoverable chiral sulphoxide

DOI: 10.1016/0040-4039(94)88346-7

Source and publish data:

Tetrahedron Letters p. 1785 - 1788 (1994)

Update date:2022-08-03

Topics:

Authors:

Linney Linney

Linney, Ian D.

Tye Tye

Tye, Heather

Wills Wills

Wills, Martin

Butlin Butlin

Butlin, Roger J.

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Article abstract of DOI:10.1016/0040-4039(94)88346-7

The enantiomerically pure cyclic sulphinamide S(S)R-(+)-3 reacts with the sodium enolates of ketones to give the corresponding homochiral sulphoxides. Reduction of the carbonyl group in these products using DIBAL-H or DIBAL- H/ZnBr₂ gives compl

Full text of DOI:10.1016/0040-4039(94)88346-7

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