Heteroatom-facilitated lithiations of N-methyl-N-(trimethylsilyl)methyl-benzylamine and benzyl (trimethylsilyl)methyl ether with butyllithium

DOI: 10.1248/cpb.41.2195

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2195 - 2196 (1993)

Update date:2022-08-03

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Authors:

Mitsui Mitsui

Marumo Marumo

Inoue-Ando

Kato Kato

Sato Sato

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Article abstract of DOI:10.1248/cpb.41.2195

Lithiation of the Si-methyl groups of N-methyl-N-[(trimethylsilyl)methyl]benzylamine (1) occurred in preference to ortho-lithiation of the benzyl group with butyllithium in ether. In a similar reaction with benzyl (trimethylsilyl)methyl ether (7), lithiat

Full text of DOI:10.1248/cpb.41.2195

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