Journal of the American Chemical Society p. 5031 - 5034 (1981)
Update date:2022-08-03
Topics:
Lee, L.
Russel, J.A.
Su, R.T.M.
Cross, R.J.
Saunders, M.
Using crossed molecular beams, we have studied the reactions of SbF5 and its polymers with organic halides (RX).Monomer SbF5 reacts with some RX species to produce R(1+) + SbF5X(1-).Dimer reacts with a wider variety of RX species to produce R(1+) + SbF6(1-) + SbF4X.Unless R(1+) is particularly subject to cleavage, only the parent R(1+) is observed; this indicates that the product is formed with only a small amount of internal energy.
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