Deproto-metallation using a mixed lithium-zinc base and computed CH acidity of 1-aryl 1H-benzotriazoles and 1-aryl 1H-indazoles

DOI: 10.1039/c3ob42380h

Source and publish data:

Organic and Biomolecular Chemistry p. 1475 - 1487 (2014)

Update date:2022-09-26

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Authors:

Nagaradja, Elisabeth

Chevallier, Floris

Roisnel, Thierry

Dorcet, Vincent

Halauko, Yury S.

Ivashkevich, Oleg A.

Matulis, Vadim E.

Mongin, Florence

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Article abstract of DOI:10.1039/c3ob42380h

1-Aryl-1H-benzotriazoles and -1H-indazoles were synthesized, and their deproto-metallation using the base prepared by mixing LiTMP with ZnCl ₂·TMEDA (1/3 equiv.) was studied. In the indazole series, reactions occurring at the 3 position were fo

Full text of DOI:10.1039/c3ob42380h

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