New Co-ordination Mode of 4,5-Dimercapto-1,3-dithiole-2-thionate(2-) in Polynuclear Gold(I) Complexes. Crystal Structures of 3-C3S5)(PPh3)3>ClO4 and

DOI: 10.1039/DT9940001325

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1325 - 1326 (1994)

Update date:2022-08-04

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Authors:

Cerrada, Elena

Laguna, Antonio

Laguna, Mariano

Jones, Peter G.

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Article abstract of DOI:10.1039/DT9940001325

The ligand 4,5-dimercapto-1,3-dithiole-2-thionate(2-) (C3S5(2-)) has been transferred from 2 to gold(I) centres, affording di-, tri- or tetra-nuclear complexes containing the C3S5(2-) ligand in unprecedented μ- or μ₃-bridging forms.

Full text of DOI:10.1039/DT9940001325

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