Journal of the Chemical Society. Chemical communications p. 439 - 440 (1984)
Update date:2022-08-04
Topics:
Ando, Takashi
Sumi, Shinjiro
Kawate, Takehiko
Ichihara, Junko
Hanafusa, Terukiyo
Ultrasonic irradiation of a mixture of benzyl bromide, potassium cyanide, and alumina in an aromatic solvent yields benzyl cyanide, whereas mechanical agitation gives the Friedel-Crafts type product; sonication changes the main reaction pathway from aromatic electrophilic to aliphatic nucleophilic substitution.
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