Synthesis and Characterization of Diethynylmethanobuckminsterfullerene, a Building Block for Macrocyclic and Polymeric Carbon Allotropes

DOI: 10.1021/jo00090a006

Source and publish data:

Journal of Organic Chemistry p. 2927 - 2929 (1994)

Update date:2022-08-05

Topics:

Authors:

An, Yi-Zhong

Rubin, Yves

Schaller, Christophe

McElvany, Stephen W.

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Article abstract of DOI:10.1021/jo00090a006

Diethynylmethanobuckminsterfullerene (1a and 13C-labeled 1b) has been prepared by reaction of the lithium salt of 1,5-bis(trimethylsilyl)-1,4-pentadiyn-3-one (p-toluenesulfonyl)hydrazone (5a/b) with C60 followed by desilylation and characterized by NMR, IR, UV-vis, and CI-TQMS spectroscopies.

Full text of DOI:10.1021/jo00090a006

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