Synthesis and Characterization of Diethynylmethanobuckminsterfullerene, a Building Block for Macrocyclic and Polymeric Carbon Allotropes

DOI: 10.1021/jo00090a006

Source and publish data:

Journal of Organic Chemistry p. 2927 - 2929 (1994)

Update date:2022-08-05

Topics:

Authors:

An, Yi-Zhong

Rubin, Yves

Schaller, Christophe

McElvany, Stephen W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00090a006

Diethynylmethanobuckminsterfullerene (1a and 13C-labeled 1b) has been prepared by reaction of the lithium salt of 1,5-bis(trimethylsilyl)-1,4-pentadiyn-3-one (p-toluenesulfonyl)hydrazone (5a/b) with C60 followed by desilylation and characterized by NMR, IR, UV-vis, and CI-TQMS spectroscopies.

Full text of DOI:10.1021/jo00090a006

Products guided by the article

Product name:1,5-bis(trimethylsilyl)-3-⁽¹³⁾C-penta-1,4-yne-3-p-tosyl hydrazone

Cas No:156370-66-0

R&D Labs maybe for 156370-66-0

NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,
Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
Acorn PharmaTech Co., Ltd

Contact:86-25-58619180

Address:Nanjing High-Tech Zone 10 Xinghuo Road Pukou District Nanjing, Jiangsu 210061 The People's Republic of China
Neworld Chemical Co., Ltd Shanghai(expird)

Contact:+86-21-62202658

Address:11F, Blvd 2, No. 1969 PuXing Rd, Shanghai
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD

Contact:+86-571-88932183

Address:Hangzhou

Relevant to this article

Multiple C-H bond cleavage of the alkyl group in (2,6-Dialkylphenoxo) ruthenium(II) complexes

Doi:10.1021/om5000248
(2014)
Synthesis of di- and tri-saccharides with intramolecular NH-glycosidic linkages: Molecules with flexible and rigid glycosidic bonds for conformational studies

Doi:10.1016/0008-6215(94)90013-2
(1994)
New zirconocenes with 4,5,6,7-tetrahydroindene ligands. Synthesis and catalytic activity in the polymerization of ethylene and copolymerization of ethylene with hex-1-ene

Doi:10.1007/s11172-016-1485-x
(2016)
Na⁺-glucose cotransporter inhibitors as antidiabetic agents. II. Synthesis and structure-activity relationships of 4'-dehydroxyphlorizin derivatives

Doi:10.1248/cpb.46.22
(1998)
Diastereoselective protonation of dienols: A formal approach to zaragozic acid C side chain

Doi:10.1016/S0957-4166(99)00102-0
(1999)
Zwitterionic pyridinium derivatives of [closo-1-CB₉H ₁₀]^- and [closo-1-CB₁₁H₁₂] ^- as high Δε additives to a nematic host

Doi:10.1039/c3tc32351j
(2014)

Article Doi