Synthesis and Characterization of Diethynylmethanobuckminsterfullerene, a Building Block for Macrocyclic and Polymeric Carbon Allotropes

DOI: 10.1021/jo00090a006

Source and publish data:

Journal of Organic Chemistry p. 2927 - 2929 (1994)

Update date:2022-08-05

Topics:

Authors:

An, Yi-Zhong

Rubin, Yves

Schaller, Christophe

McElvany, Stephen W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00090a006

Diethynylmethanobuckminsterfullerene (1a and 13C-labeled 1b) has been prepared by reaction of the lithium salt of 1,5-bis(trimethylsilyl)-1,4-pentadiyn-3-one (p-toluenesulfonyl)hydrazone (5a/b) with C60 followed by desilylation and characterized by NMR, IR, UV-vis, and CI-TQMS spectroscopies.

Full text of DOI:10.1021/jo00090a006

Products guided by the article

Product name:1,5-bis(trimethylsilyl)-3-⁽¹³⁾C-penta-1,4-yne-3-p-tosyl hydrazone

Cas No:156370-66-0

R&D Labs maybe for 156370-66-0

Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
ShangHai Soyoung Biotechnology Inc

website:http://www.soyoungbio.com

Contact:+86-21-69893009

Address:shanghai

Relevant to this article

Multiple C-H bond cleavage of the alkyl group in (2,6-Dialkylphenoxo) ruthenium(II) complexes

Doi:10.1021/om5000248
(2014)
Synthesis of di- and tri-saccharides with intramolecular NH-glycosidic linkages: Molecules with flexible and rigid glycosidic bonds for conformational studies

Doi:10.1016/0008-6215(94)90013-2
(1994)
New zirconocenes with 4,5,6,7-tetrahydroindene ligands. Synthesis and catalytic activity in the polymerization of ethylene and copolymerization of ethylene with hex-1-ene

Doi:10.1007/s11172-016-1485-x
(2016)
Na⁺-glucose cotransporter inhibitors as antidiabetic agents. II. Synthesis and structure-activity relationships of 4'-dehydroxyphlorizin derivatives

Doi:10.1248/cpb.46.22
(1998)
Diastereoselective protonation of dienols: A formal approach to zaragozic acid C side chain

Doi:10.1016/S0957-4166(99)00102-0
(1999)
Zwitterionic pyridinium derivatives of [closo-1-CB₉H ₁₀]^- and [closo-1-CB₁₁H₁₂] ^- as high Δε additives to a nematic host

Doi:10.1039/c3tc32351j
(2014)

Article Doi