Nonphotochemical synthesis and structure of the first donor-stabilized [bis(silylene)]ruthenium complex

DOI: 10.1021/om00019a003

Source and publish data:

Organometallics p. 2545 - 2547 (1994)

Update date:2022-07-29

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Authors:

Tobita, Hiromi

Wada, Hiroaki

Ueno, Keiji

Ogino, Hiroshi

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Article abstract of DOI:10.1021/om00019a003

The first donor-stabilized [bis(silylene)]ruthenium compex, Cp(Ph₃P)Ru(SiMe₂ - O(Me) - SiMe₂), has been synthesized by the thermal reaction of CpRu(PPh₃)₂Me with HMe₂SiSiMe₂OMe. The X-ray crystal structure analysis of this complex revealed its distorted-piano-stool structure, containing a RuSi₂O four-membered chelate ring with two short Ru-Si bonds and two long Si-O bonds.

Full text of DOI:10.1021/om00019a003

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