Tetrahedron Letters p. 1313 - 1316 (1994)
Update date:2022-07-29
Topics:
Yang, Ge
Myles, David C.
An approach to the C-13 to C-21 sector if the immunosuppressive marine natural product discodermolide (1) is described.The C-15 to C-16 bond is formed by diastereoselective alkylation of a ketone enolate.Either diastereomer of alkylation can be obtained by selecting the appropriate counter ion.The C-16 to C-21 subunit is prepared in two steps from 11.
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Doi:10.1002/anie.201800385
(2018)Doi:10.1021/jo402586v
(2014)Doi:10.1002/ejoc.201900117
(2019)Doi:10.1021/ja001087r
(2001)Doi:10.1016/S0040-4020(01)80705-5
(1994)Doi:10.1016/S0040-4020(01)89369-8
(1994)
