
Archiv der Pharmazie p. 143 - 155 (1994)
Update date:2022-08-04
Topics:
Kucklander
Lessel
Poll
The labile quinonylalkylenaminones 10a-c and 11a-c are synthesized and cyclized to the products 17, 21 and 22a-c. In solution the tricyclic systems 22a-c react to spirocompounds 19a-c and 20a-c. The structure of 22a is confirmed by X-ray analysis. Semiempiric quantum chemical calculations and Pearson's concept of hard and soft acids and bases are used to explain the observed reactions.
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Doi:10.1016/0022-328X(94)80163-0
(1994)Doi:10.1016/j.tetlet.2020.152751
(2021)Doi:10.1021/acs.jmedchem.0c01638
(2020)Doi:10.1021/jo00091a038
(1994)Doi:10.1016/S0040-4039(03)00732-9
(2003)Doi:10.1002/ejoc.201501083
(2015)