Archiv der Pharmazie p. 143 - 155 (1994)
Update date:2022-08-04
Topics:
Kucklander
Lessel
Poll
The labile quinonylalkylenaminones 10a-c and 11a-c are synthesized and cyclized to the products 17, 21 and 22a-c. In solution the tricyclic systems 22a-c react to spirocompounds 19a-c and 20a-c. The structure of 22a is confirmed by X-ray analysis. Semiempiric quantum chemical calculations and Pearson's concept of hard and soft acids and bases are used to explain the observed reactions.
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Doi:10.1016/0022-328X(94)80163-0
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