Journal of Organic Chemistry p. 3442 - 3444 (1994)
Update date:2022-08-04
Topics:
Taber, Douglas F.
Bhamidipati, Rama S.
Thomas, Mitchell L.
Asymmetric dihydroxylation of epoxide 12 led, via biomimetic epoxide opening, to tetrahydrofuran 13.Acetylation of 13 then gave the antibiotic terpene (+)-tuberine (14).In the course of this work, the absolute configuration of (+)-tuberine was corrected.
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