Stereoconvergent 'One-Pot' Tandem -Wittig-Anionic Oxy-cope Rearrangement of Acyclic Bis-Allylic Ethers in the Diastereoselective Synthesis of Substituted Tetrahydropyrans

DOI: 10.1039/c39940001469

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1469 - 1470 (1994)

Update date:2022-07-30

Topics:

Authors:

Greeves, Nicholas

Vines, Katya Jane

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940001469

The unsaturated alcohols derived from a 'one-pot' tandem <2,3>-Wittig-anionic oxy-Cope (AOC) rearrangement undergo a halocyclisation reaction with iodine in acetonitrile to give substituted tetrahydropyrans with a high degree of stereocontrol.

Full text of DOI:10.1039/c39940001469

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[(E)-3-((Z)-1-Isopropyl-hept-2-enyloxy)-propenyl]-benzene

Cas No:156838-67-4

R&D Labs maybe for 156838-67-4

HANWAYS CHEMPHARM CO.,LIMITED

website:http://www.hanwayschem.com

Contact:+86-18502787239(whatsapp)-

Address:18-1-802, Green Garden, Jianghan District, Wuhan 430023, China
Yuan Shi(SuQian)Biotechnology Co.,Ltd

website:http://www.yuanshibio.com

Contact:+86-527-84226672

Address:jiangsu suqian
Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Jinan Jianfeng Chemical Co., Ltd

Contact:0086-531-88110457

Address:sales01(-a-t-)pharmachemm{dot}c+o+m

Relevant to this article

Synthesis of isoxazole moiety containing ferrocene derivatives and preliminarily in vitro anticancer activity

Doi:10.1039/c4md00151f
(2014)
Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(ii)-OOH species and a copper mediated NO reductive coupling reaction

Doi:10.1039/c3cc47942k
(2014)
Highly stereoselective synthesis and structural confirmation of a fungal metabolite, LL-P880β

Doi:10.1248/cpb.42.179
(1994)
Diastereotropic phenomena for the appearance of SmCA* phase in α-trifluoromethyl-β-methyl-substituted liquid crystalline molecules

Doi:10.1246/cl.1996.861
(1996)
Characterization and structure–property relationships of organic–inorganic hybrid composites based on aluminum–magnesium hydroxycarbonate and azo chromophore

Doi:10.3390/molecules24050880
(2019)
Synthesis, crystal structure, spectroscopic, thermogravimetric and theoretical characterization of Ni(II) and Zn(II) complexes with 4-chloro-2-nitrobenzenesulfonamide

Doi:10.1016/j.molstruc.2013.11.058
(2014)

Article Doi