Stereoconvergent 'One-Pot' Tandem -Wittig-Anionic Oxy-cope Rearrangement of Acyclic Bis-Allylic Ethers in the Diastereoselective Synthesis of Substituted Tetrahydropyrans

DOI: 10.1039/c39940001469

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1469 - 1470 (1994)

Update date:2022-07-30

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Authors:

Greeves, Nicholas

Vines, Katya Jane

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Article abstract of DOI:10.1039/c39940001469

The unsaturated alcohols derived from a 'one-pot' tandem <2,3>-Wittig-anionic oxy-Cope (AOC) rearrangement undergo a halocyclisation reaction with iodine in acetonitrile to give substituted tetrahydropyrans with a high degree of stereocontrol.

Full text of DOI:10.1039/c39940001469

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