The detailed mechanism for the reaction of bare iron(I) ions with tert-butyl cyanide and isocyanide in the gas phase

DOI: 10.1021/om00109a040

Source and publish data:

Organometallics p. 1820 - 1822 (1989)

Update date:2022-08-02

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Authors:

Eller, Karsten

Schwarz, Helmut

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Article abstract of DOI:10.1021/om00109a040

Experimental, evidence is presented demonstrating that bare Fe⁺ does not insert in the C-X bond of (CH₃)₃C-X (X = CN, NC). Rather, initial "end-on" complexation of the functional group induces cleavage of this bond which i

Full text of DOI:10.1021/om00109a040

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