
Tetrahedron Letters p. 2465 - 2468 (1994)
Update date:2022-08-02
Topics:
Barry, John
Kodadek, Thomas
A new synthesis of D4-symmetric porphyrins is presented which provides chiral macrocycles in only five step starting from optically active cyclic ketones.The efficacy of this approach is demonstrated with the synthesis of a new porphyrin derived from R-(+)-nopinone.The development of this flexible and general route should speed the development of porphyrin-based asymmetric catalysts.
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Doi:10.1016/j.tet.2015.05.115
(2015)Doi:10.1021/jm00052a010
(1994)Doi:10.1039/d1ob00942g
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(1994)